Methyl Hydrogen Silicone Fluid
Methyl Hydrogen Silicone Fluid

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Methyl hydrogen siloxane serves as a high-efficiency textile auxiliary, enhancing processing performance through its unique reactivity and surface properties. This specialty silicone oil significantly improves fiber lubrication, reducing breakage during spinning and weaving while increasing production efficiency.

Its exceptional spreading capability ensures even distribution of dyes and finishing agents, particularly on synthetic fibers and challenging textile surfaces, enhancing color fastness while reducing chemical usage by 20-30%. In waterproof finishing applications, it forms durable cross-linked networks that provide excellent water resistance while maintaining fabric breathability.

With heat resistance up to 200°C, it is suitable for high-temperature setting processes, while its complete volatility ensures no residue. Compatible with both natural and synthetic fibers, it offers textile manufacturers a sustainable solution for improving product quality and reducing costs.

Basic Product Information

  • Product Name: Methyl hydrogen siloxane
  • Appearance: Colorless to pale yellow transparent oily liquid.

TYPICAL PROPERTIES

Appearancecolorless transparent liquid
Viscosity (25℃),mm2/s20-250
H% (wt)0.04-1.45
Volatile content(150℃,3h),%≤11

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Physical Properties

Low Viscosity: 50–500 cSt

High-Temperature Resistance: Stable from -30°C to 200°C

Excellent Spreadability: Ensures uniform surface coverage

Chemical Properties

Reactive Si-H Bonds: Enable the formation of durable functional films on fiber surfaces via cross-linking reactions, enhancing material durability.

Product Functions

  • Water & Oil Repellent Treatment

Imparts durable water and oil repellency to fabrics.

  • Softening & Smoothing Treatment

Significantly enhances fabric hand feel and improves smoothness.

  • Antistatic Treatment

Reduces fiber friction-induced static electricity, enhancing wearing comfort.

  • Abrasion Resistance Enhancement

Reduces fiber abrasion and extends textile service life.

methyl hydrogen siloxane
methylhydrogensiloxane

Applications

  • Apparel Fabrics: Outdoor jackets, sportswear, premium suits.
  • Home Textiles: Upholstery fabrics, curtains, bedding.
  • Industrial Textiles: Filter materials, protective clothing, automotive interiors.
  • Specialty Fabrics: Medical textiles, flame-retardant fabrics.

Core Advantages

AdvantageTextile ValueData Support
Durable Water ResistanceWater repellency retention >90% after 50 washesWater contact angle ≥130° (AATCC 22)
Ultra-Soft Hand Feel40% improvement in fabric softnessValidated by sensory evaluation + mechanical testing
Energy EfficiencyLow-temperature curing (120°C × 1 min)30% energy saving vs. conventional processes
Multifunctional IntegrationSingle-step process achieves waterproofing + softening + antibacterial effectsPasses ISO 20743 antibacterial testing
Eco-SafetyPFOS/PFOA-free; compliant with ZDHC standardsOEKO-TEX® Class I certification

Market Value

Global Market Overview

  • Market Size

2023 Market Size: USD 380–420 million

Share of Textile Auxiliaries Market: 12–15%

Projected 2025 Size: USD 500–550 million (CAGR 8–10%)

  • Regional Distribution

Asia-Pacific Dominance (65%): China accounts for 55% of global production capacity.

Europe’s Premium Market: Commands 30–50% price premium.

North America’s Technological Leadership: Holds 40% of global patents.

Technological Innovation Value

  • Eco-Friendly Product Development

Solvent-Free Formulations:

Water-based emulsions with ≥40% solid content

VOC content ≤50 g/L

Biodegradability:≥60% degradation rate within 28 days

EU Eco-label certified products

  • High-Performance Modification Technologies

Hyperbranched Structures:

Molecular weight distribution ≤1.05

30% improvement in finishing efficacy

Nano-Composite Systems:

SiO₂ nanoparticle reinforcement

5–8× enhancement in abrasion resistance

  • Smart Functionalization

Thermochromic Applications:

Color transition range: 30–40°C

Emerging market in sportswear

Humidity-Responsive Materials:

Moisture permeability change ≥3000 g/m²/24h

Dedicated products for medical dressings

Development Trends & Forecasts

  • Technology Directions

Bio-based Raw Materials:

30% substitution with castor oil derivatives

40% reduction in carbon footprint

Digital Twin Integration:

50% efficiency gain in process optimization

60% shorter product development cycles

  • Market Opportunities

Sustainable Fashion:

Growing demand for recycled fiber treatments

Estimated 2025 market size: USD 280 million

Medical Textiles:

Antiviral functional products

CAGR 15–18%

  • Policy Drivers

China’s 14th Five-Year Plan:

Green manufacturing subsidies

20% stricter energy efficiency standards

EU REACH Regulations:

2025 restricted substance list update

8–10% increase in compliance costs

Experimental Data & Case Studies

Outdoor Apparel Applications

  • Experimental Data:

Hydrostatic Resistance: >10,000 mm (ISO 811)

Moisture Permeability: >8,000 g/m²/24h (ASTM E96)

Tested on hydrogen silicone oil-treated outerwear fabrics.

  • Case Study:

Leading International Outdoor Brand:

Adopted hydrogen silicone oil finishing agent, achieving BlueSign® certification and driving 35% sales growth.

Luxury Home Textile Applications

  • Experimental Data:

Friction Coefficient: Reduced to 0.15 (untreated: 0.35)

Anti-Pilling Performance: Improved to Grade 4–5 (GB/T 4802.1)

Tested on hydrogen silicone oil-treated silk fabrics.

  • Case Study:

Premium Home Textile Brand:

Applied to high-end bedding series, resulting in 50% increase in customer repurchase rate.

Medical Textile Applications

  • Experimental Data:

Blood Penetration Resistance: >5 min (YY/T 0506)

Bacterial Barrier Rate: >99% (ISO 22610)

Tested on surgical drapes with hydrogen silicone oil coatings.

  • Case Study:

Top 3 Domestic Medical Dressing Manufacturer:

Replaced imported products, achieving 40% cost reduction while maintaining performance.

Preparation Process, Core Technologies & Precautions

Preparation Process

  • Basic Synthesis Process

Raw Material System:

Primary Raw Materials:

Dimethyl dichlorosilane (≥99.8% purity)

Methyl hydrogen dichlorosilane (hydrogen content ≥99.5%)

Auxiliary Materials:

Hexamethyldisiloxane (end-capping agent)

Platinum-based catalyst (Pt content: 50–100 ppm)

  • Hydrolysis & Polycondensation

Process Parameters:

Temperature control: 25–30°C (±0.5°C)

pH adjustment: 4.5–5.5 (acetic acid/sodium acetate buffer system)

Molar ratio: Si-H/Si-CH₃ = 0.15–0.35

Key Equipment:

Enamel reactor (with variable-frequency stirring)

Online pH monitoring system

  • Molecular Weight Control

Chain Termination:

Hexamethyldisiloxane dosage: 1–3%

Molecular weight distribution (PDI ≤1.25)

Process Optimization:

Stepwise heating (30°C → 60°C → 90°C)

Vacuum devolatilization (-0.095 MPa, 120°C)

Functional Modification Technologies

  • Polyether Modification

Grafting Process:

Allyl polyoxyethylene ether (EO/PO = 3:1)

Platinum-catalyzed addition (80–90°C, 4–6h)

Performance Metrics:

Cloud point (1% aqueous solution) ≥95°C

Surface tension ≤22 mN/m

  • Amino Modification

Reaction System:

Allylamine (primary amine content ≥90%)

Isopropanol solvent system

Key Controls:

Amine value: 0.8–1.2 mmol/g

Yellowing index ≤1.5 (ΔYI)

  • Epoxy Modification

Key Techniques:

Glycidyloxypropyltrimethoxysilane

Solvent-based reaction (toluene reflux)

Application Properties:

Epoxy value: 0.25–0.35 eq/100g

40% improvement in cotton fiber binding strength

Core Process Technologies

  • Precision Hydrogen Content Control

Analytical Methods:

Infrared spectroscopy (Si-H characteristic peak at 2160 cm⁻¹)

Chemical titration (accuracy ±0.02%)

Control Methods:

Fine-tuning raw material ratios (±0.5%)

Reaction termination timing control

  • Low-Viscosity Technology

Process Innovations:

Molecular sieve selective adsorption (3Å pore size)

Supercritical CO₂ extraction (pressure: 8–10 MPa)

Product Specifications:

Viscosity at 25°C: 50–100 cSt

Volatile content ≤0.3%

  • Microemulsification Technology

Emulsification System:

Nonionic surfactant (HLB 12–14)

Co-emulsifier (C₈–C₁₀ alcohol)

Process Parameters:

High-pressure homogenization (80–100 MPa)

Particle size distribution (D90 ≤100 nm)

Precautions

Avoid direct mixing with cationic auxiliaries.

Storage temperature: 5–30°C; prevent freezing.

Packaging & Ordering

Packaging: 200kg/1000kg plastic drums (customizable).

Factory Products

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Contact Information

Address

No. 116, Jiangdong Street, Yiwu City, Jinhua City, Zhejiang Province,China

Phone

+86 18807097967

Email

silicone1985@gmail.com

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