A Chinese Enterprise Filed a Patent for a Preparation Method of LowViscosity, LowCyclosiloxane α,ωDihydrogenTerminated Polydimethylsiloxane - Methyl Hydrogen Silicone Fluid Factory
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According to information from the China National Intellectual Property Administration (CNIPA), a company recently filed a patent entitled LowViscosity, LowCyclosiloxane α,ωDihydrogenTerminated Polydimethylsiloxane and Its Preparation Method. The publication number is CN122563083A, the application number is CN202610961581.8, the publication date is August 14, 2026, and the filing date is June 30, 2026.
The patent abstract indicates that the present invention provides a lowviscosity, lowcyclosiloxane α,ωdihydrogenterminated polydimethylsiloxane and its preparation method, falling within the technical field of organosilicon materials. The preparation method comprises: subjecting hydroxylterminated polydimethylsiloxane oligomers to a dehydration polycondensation reaction in the presence of a thermoresponsive polyphosphazenebased catalyst to produce highviscosity polydimethylsiloxane; wherein the thermoresponsive polyphosphazenebased catalyst is a linear chlorophosphazene surfacegrafted with a thermoresponsive polymer; adding hydrogencontaining disiloxane capping agent into the reaction system in 36 batches, and carrying out chainscission and grafting reactions under a gradient cooling procedure; after the reaction is completed, cooling the system to a temperature below the LCST (Lower Critical Solution Temperature) to deactivate the thermoresponsive polyphosphazenebased catalyst, so as to obtain the target lowviscosity, lowcyclosiloxane α,ωdihydrogenterminated polydimethylsiloxane. By adopting the thermoresponsive polyphosphazene catalyst combined with the chainscissiongrafting reaction via batch feeding of hydrogencontaining disiloxane capping agent and the gradientcooling procedure, the prepared hydrogenterminated silicone oil features low viscosity and low cyclosiloxane content, together with narrow molecularweight distribution, a small polydispersity index (PDI), high homogeneity and stable performance.
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